Dr. Silvina Tomassone
The Levich Institute
City College of CUNY
"Molecular Dynamics Simulations of Gaseous-Liquid Phase Transitions
of Soluble and Insoluble Surfactants at a Fluid Interface"
ABSTRACT
Although medium chain length insoluble amphiphiles are well known to
form gaseous and liquid expanded phases on an air/water interface, the
situation for the soluble case is less clear.
We perform molecular dynamics simulations
of model surfactant molecules dissolved in a bulk liquid solvent
in coexistence with its vapor. Our results indicate a transition in
both soluble and insoluble surfactants: a plateau in surface tension vs.
surface coverage, whose instantaneous configurations display two phase
coexistence, along with correlation functions indicating a transition to
gaseous to liquid-like behavior.
BRIEF ACADEMIC/EMPLOYMENT HISTORY:
Ph.D. in Physics, Northeastern University, 1998. Advisors: Prof. J. Krim and Prof. Sokoloff
1994-1998, Northeastern University, Boston, Teaching Research Assistant.
1999-present, Levich Institute, CCNY, New York, Postdoctoral Fellow