Levich Institute Seminar Announcement, 04/15/2008

Tuesday, 04/15/2008 4:00 PM Mudd Building, Room #825 500 West 120th Street Columbia University Professor John Brady California Institute of Technology Department of Chemical Engineering "Osmotic Propulsion: The Osmotic Motor" [This is a CCNY/Columbia NSF-IGERT Soft Materials seminar]

ABSTRACT

A model for self-propulsion of a colloidal particle – the osmotic motor – immersed in a dispersion of colloidal ‘bath’ particles is presented. The non-equilibrium concentration of bath particles induced by a surface reaction creates an ‘osmotic pressure’ imbalance on the motor causing it to move to regions of lower concentration. The departure of the bath particle concentration from equilibrium is characterized by the ratio between the surface reaction velocity and the diffusion velocity. The computed bath particle concentration distribution is used to calculate the driving force on the motor, from which the self-induced osmotic velocity is determined via application of Stokes drag law. For slow reactions the self-propulsion is determined by the reaction velocity. When surface reaction dominates over diffusion the osmotic velocity cannot exceed the diffusive speed of the bath particles. The implications of these features for different bath particle volume fractions and particle sizes are discussed. Theoretical predictions are compared with Brownian Dynamics simulations.

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